Trim fat from chops. Coat a large nonstick skillet with cooking spray and place over medium-high heat until hot.
Add chops and cook 2 minutes on each side. Remove from skillet and set aside.
Combine rice, water, onion, pepper, tomatoes and tomato sauce in skillet. Bring to a boil.
Arrange chops over rice mixture. Cover, reduce heat and cook 5-10 minutes or until liquid is absorbed and rice and pork are done and pork has reached 160 degrees F.